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In each Release Event for Structure Deck: Fire Kings , Duelists can purchase a brand new Structure Deck to be in with a chance to obtain an exclusive Game Mat

Fusion Summon 1 "Supreme King Z-ARC" from your Extra Deck by banishing Fusion Materials mentioned on it from your hand, Deck, Extra Deck, field, and/or GY, but negate its effects unless at least 1 each of your "Pendulum Dragon", "Xyz Dragon", "Synchro Dragon", and "Fusion Dragon" monsters are currently banished

You can also unlock a secret pack by crafting a UR card, though it seems there may be some limitations on that

Judai is happy-go-lucky and eager to prove himself